Two new piperidine alkaloids, pipernonaline and piperundecalidine, were isolated from fruits of Piper longum L. (Piperaceae). Their structures were determined to be (2E, 8E)-N-[9-(3,4-methylenedioxyphenyl)-2,8-nonadienoyl]piperidine and (2E, 4E, 10E)-N-[11-(3,4-methylenedioxyphenyl)-2,4,10-undecatrienoyl]piperidine, respectively, on the basis of spectral data.