Enantioselective Synthesis of the [6,6] Spiroketal Core of Reveromycin A

Enantioselective Synthesis of the [6,6] Spiroketal Core of Reveromycin A Reveromycin A biosynthesis uses RevG and RevJ for stereospecific spiroacetal formation Reveromycins, new inhibitors of eukaryotic cell growth. III. Structures of reveromycins A, B, C and D. Cleavage of Four Carbon−Carbon Bonds during Biosynthesis of the Griseorhodin A Spiroketal Pharmacophore Structure of the New Spiroketal-Macrolide A82548A. Alchivemycin A, a Bioactive Polycyclic Polyketide with an Unprecedented Skeleton from <i>Streptomyces</i> sp. Design and synthesis of 2-phenyl-1,4-dioxa-spiro[4.5]deca-6,9-dien-8-ones as potential anticancer agents starting from cytotoxic spiromamakone A Structure of the Spiroketal-macrolide Ossamycin. Stereoselective Synthesis of Core Structure of Cortistatin A Eleganketal A, a Highly Oxygenated Dibenzospiroketal from the Marine-Derived FungusSpicaria elegansKLA03