The chemical constituents of Australian Flindersia species. XXI. An examination of the bark and the leaves of F. laevicarpa

Australian Journal of Chemistry
1976.0

Abstract

<jats:p>From extracts of the bark of Flindersia laevicarpa C. T. White &amp; Francis (Rutaceae), the known substances lupeol, β-sitosterol, hesperidin and salicylic acid were isolated together with eight othersubstances. Three of them, flindercarpin-1, C25,H22O11, flindercarpin-2, C32H40O13,and flindercarpin-3, C26H32O9, were reserved for further study. The others were shown to be (-)-nerolidol,(+)-threo-1,5-diphenylpentane-1,3-diol, 2-(2-pheny1ethyl)chromone (flindersiachromone), its 2,3-dihydro derivative, and its 8-methoxy derivative (8-methoxyflindersiachromone).The leaves yielded hesperidin, flindercarpin-2, harmalan and five other products. A triterpene, flindersolide, C30H48O4, was reserved for further study. Acetylation of the harmalan mother liquors gave acetylharmalan, a mixture of dimers of the latter and also N-[2-(2-acetyl-3-indolyl)ethyl]acetamide, all of which are artefacts. The remaining substance, a flavone, carpachromene, C20H16O5, was shown to be 5-hydroxy-8-(4-hydroxyphenyl)-2,2-dimethyl-2H,6H-benzo[1,2-b:5,4-b']dipyran-6-one.

Knowledge Graph

Similar Paper

The chemical constituents of Australian Flindersia species. XXI. An examination of the bark and the leaves of F. laevicarpa
Australian Journal of Chemistry 1976.0
Chemical constituents of the Flindersia. XXIII. Determination of the structure of flindercarpin-2 as methyl (S)-(Acetoxy){[3'S-(3α,3aα,4α,5β,6α,6aα,7α,10aα,11aα)]-5',6'-diacetoxy-7'-(furan-3'-yl)-2',2',3a',6a', 11a'-pentamethyl-12'-methylene-9'-oxo-2',3',3a',4',5',6',6a',9', 10', 11a'-decahydro-7'H-4', 10a'-methano-10a'H-furo[2,3-b]pyrano[3,4-g]oxocin-3'-yl)acetate
Australian Journal of Chemistry 1984.0
The chemical constituents of Australian Flindersia species. V. The constituents of Flindersia maculosa Lindl
Australian Journal of Chemistry 1954.0
The chemical constituents of Australian Flindersia species. V. The constituents of Flindersia maculosa Lindl
Australian Journal of Chemistry 1954.0
The chemical constituents of Australian Flindersia species. XX. An examination of F. pimenteliana
Australian Journal of Chemistry 1975.0
The Chemical Constituents of Australian Flindersia Species. I. Collinin, 7-Geranoxy-8-methoxycoumarin
Australian Journal of Chemistry 1949.0
The Chemical Constituents of Australian Zanthoxylum Species. VI. A Further Examination of the Constituents of the Bark of Zanthoxylum conspersipunctatum (Rutaceae)
Australian Journal of Chemistry 1973.0
Some extractives of Melicope octandra (Rutaceae)
Australian Journal of Chemistry 1976.0
The chemical constituents of Australian Zanthoxylum species. V. The constituents of Z. pluviatile Hartley; the structures of two new lignans
Australian Journal of Chemistry 1970.0
The chemical constituents of Australian Flindersia species. VI. The structure and chemisty of Flindersine
Australian Journal of Chemistry 1954.0