Dammarane and cycloartane triterpenoids from three Rapanea species

Phytochemistry
1992.0

Abstract

An investigation of three species of Rapanea, R. umbellata, R. lancifolia and R. guyanensis, has led to the identification of three terpeno-p-hydroxybenzoic acids, 3-geranyl-4-hydroxy-5-(3'',3''-dimethylallyl)-benzoic acid; 5-carboxy-7-(3'',3''-dimethylallyl)-2-(1'-hydroxy-1',5'-dimethylhex-4'-enyl)-2,3-dihydrobenzofuran and 6-carboxy-8-(3'',3''-dimethylallyl)-3α-hydroxy-2α-methyl-2-(4'-methylpent-3'-enyl)-3,4-dihydrobenzopyran and two triterpenoids which appear to be novel. The two new compounds were identified on the basis of spectroscopic analysis as 24(E)-3-oxo-dammara-20,24-dien-26-al and 24(E)-3α-hydroxycycloart-24-en-26-al.

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