Fourteen alkaloids have been isolated from bulbs of Boophane pava. The alkaloids, buflavine, 8-0-demethylbuflavine and montabuphine are reported here for the first time. The structure and stereochemistry of these new alkaloids were established by physical and spectroscopic methods. H-1 and C-13 NMR spectra of epivittatine and epibuphanisine were completely assigned by means of 2-D NMR techniques.