Amiaspochalasins A–H, Undescribed Aspochalasins with a C-21 Ester Carbonyl from Aspergillus micronesiensis

The Journal of Organic Chemistry
2019.0

Abstract

Amiaspochalasins A-H (1-8), eight undescribed aspochalasins, and trichalasin D (9), a known analogue, were isolated from the solid culture of Aspergillus micronesiensis. Compounds 1-9 are aspochalasins with a C-21 ester carbonyl, and their structures were determined by spectroscopic data, X-ray crystallographic analyses, electronic circular dichroism calculations, and chemical methods. The CH

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