<jats:title>Abstract</jats:title><jats:p>Chemical examination of the BuOH extract of the leaves and twigs of <jats:italic>Litsea glutinosa</jats:italic> collected from Xishuangbanna resulted in the isolation of two new aporphine alkaloids, namely litseglutine A (<jats:bold>1</jats:bold>) and B (<jats:bold>2</jats:bold>), along with two known aporphine alkaloids, boldine (<jats:bold>3</jats:bold>) and laurolitsine (<jats:bold>4</jats:bold>). The structures of the new alkaloids have been elucidated on the basis of spectra analysis as 6‐demethyl‐9‐methoxy‐1,2‐(methylenedioxy)aporphin‐10‐ol (=6,7,7a,8‐tetrahydro‐10‐methoxy‐5<jats:italic>H</jats:italic>‐benzo[<jats:italic>g</jats:italic>]‐1,3‐benzodioxolo[6,5,4‐<jats:italic>de</jats:italic>]quinolin‐11‐ol; <jats:bold>1</jats:bold>) and 1,10,11‐trimethoxyaporphin‐2‐ol (=5,6,6a,7‐tetrahydro‐1,10,11‐trimethoxy‐6‐methyl‐4<jats:italic>H</jats:italic>‐dibenzo[<jats:italic>de</jats:italic>,<jats:italic>g</jats:italic>]quinolin‐2‐ol; <jats:bold>2</jats:bold>).