9, 21-Didehydroryanodine: a new principal toxic constituent of the botanical insecticide Ryania

Journal of the Chemical Society, Chemical Communications
1984.0

Abstract

A major insecticidal constituent of Ryania speciosa is isolated and characterized by n.m.r. and mass spectroscopy as the new alkaloid 9,21-didehydroryanodine (2); reduction of (2) with hydrogen (or tritium) gas yields both ryanodine (1) and 9-epiryanodine (3) (or their 9,21-3H analogues) in a 1:9 ratio.

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