Genome Mining for Mycemycin: Discovery and Elucidation of Related Methylation and Chlorination Biosynthetic Chemistries

Genome Mining for Mycemycin: Discovery and Elucidation of Related Methylation and Chlorination Biosynthetic Chemistries Identification and Characterization of Mycemycin Biosynthetic Gene Clusters in Streptomyces olivaceus FXJ8.012 and Streptomyces sp. FXJ1.235 Biosynthesis of 2′-<i>O</i>-Methylmyxalamide D in the Myxobacterium<i>Cystobacter fuscus</i>: a Polyketide Synthase-Nonribosomal Peptide Synthetase System for the Myxalamide D Skeleton and a Methyltransferase for the Final<i>O</i>-Methylation Characterization of the Xiamenmycin Biosynthesis Gene Cluster in Streptomyces xiamenensis 318 Genomics-Driven Discovery of Benzoxazole Alkaloids from the Marine-Derived Micromonospora sp. SCSIO 07395 Utilization of the Methoxymalonyl-Acyl Carrier Protein Biosynthesis Locus for Cloning the Oxazolomycin Biosynthetic Gene Cluster from <i>Streptomyces albus</i> JA3453 Crocadepsins—Depsipeptides from the Myxobacterium <i>Chondromyces crocatus</i> Found by a Genome Mining Approach Cloning and Characterization of Genes Encoded in dTDP-&amp;lt;italic&amp;gt;D&amp;lt;/italic&amp;gt;-mycaminose Biosynthetic Pathway from a Midecamycin-producing Strain, &amp;lt;italic&amp;gt;Streptomyces mycarofaciens&amp;lt;/italic&amp;gt; Cyclofaulknamycin with the Rare Amino Acid D-capreomycidine Isolated from a Well-Characterized Streptomyces albus Strain Structure, Total Synthesis, and Biosynthesis of Chloromyxamides: Myxobacterial Tetrapeptides Featuring an Uncommon 6‐Chloromethyl‐5‐methoxypipecolic Acid Building Block