Genomics-driven discovery of the pneumocandin biosynthetic gene cluster in the fungus Glarea lozoyensis

BMC Genomics
2013.0

Abstract

<jats:title>Abstract</jats:title><jats:sec><jats:title>Background</jats:title><jats:p>The antifungal therapy caspofungin is a semi-synthetic derivative of pneumocandin B<jats:sub>0</jats:sub>, a lipohexapeptide produced by the fungus<jats:italic>Glarea lozoyensis</jats:italic>, and was the first member of the echinocandin class approved for human therapy. The nonribosomal peptide synthetase (NRPS)-polyketide synthases (PKS) gene cluster responsible for pneumocandin biosynthesis from<jats:italic>G. lozoyensis</jats:italic>has not been elucidated to date. In this study, we report the elucidation of the pneumocandin biosynthetic gene cluster by whole genome sequencing of the<jats:italic>G. lozoyensis</jats:italic>wild-type strain ATCC 20868.</jats:sec><jats:sec><jats:title>Results</jats:title><jats:p>The pneumocandin biosynthetic gene cluster contains a NRPS (GLNRPS4) and a PKS (GLPKS4) arranged in tandem, two cytochrome P450 monooxygenases, seven other modifying enzymes, and genes for L-homotyrosine biosynthesis, a component of the peptide core. Thus, the pneumocandin biosynthetic gene cluster is significantly more autonomous and organized than that of the recently characterized echinocandin B gene cluster. Disruption mutants of GLNRPS4 and GLPKS4 no longer produced the pneumocandins (A<jats:sub>0</jats:sub>and B<jats:sub>0</jats:sub>), and the<jats:italic>Δglnrps4</jats:italic>and<jats:italic>Δglpks4</jats:italic>mutants lost antifungal activity against the human pathogenic fungus<jats:italic>Candida albicans</jats:italic>. In addition to pneumocandins, the<jats:italic>G. lozoyensis</jats:italic>genome encodes a rich repertoire of natural product-encoding genes including 24 PKSs, six NRPSs, five PKS-NRPS hybrids, two dimethylallyl tryptophan synthases, and 14 terpene synthases.</jats:sec><jats:sec><jats:title>Conclusions</jats:title><jats:p>Characterization of the gene cluster provides a blueprint for engineering new pneumocandin derivatives with improved pharmacological properties. Whole genome estimation of the secondary metabolite-encoding genes from<jats:italic>G. lozoyensis</jats:italic>provides yet another example of the huge potential for drug discovery from natural products from the fungal kingdom.</jats:sec>

Knowledge Graph

Similar Paper

Genomics-driven discovery of the pneumocandin biosynthetic gene cluster in the fungus Glarea lozoyensis
BMC Genomics 2013.0
Functional Operons in Secondary Metabolic Gene Clusters in <i>Glarea lozoyensis</i> (Fungi, Ascomycota, Leotiomycetes)
mBio 2015.0
Echinocandin B biosynthesis: a biosynthetic cluster from Aspergillus nidulans NRRL 8112 and reassembly of the subclusters Ecd and Hty from Aspergillus pachycristatus NRRL 11440 reveals a single coherent gene cluster
BMC Genomics 2016.0
Discovery and development of first in class antifungal caspofungin (CANCIDAS®)—A case study
Nat. Prod. Rep. 2013.0
Acurin A, a novel hybrid compound, biosynthesized by individually translated PKS- and NRPS-encoding genes in Aspergillus aculeatus
Fungal Genetics and Biology 2020.0
Pneumocandins from Zalerion arboricola. I. Discovery and isolation.
The Journal of Antibiotics 1992.0
Genomics-Driven Discovery of Phytotoxic Cytochalasans Involved in the Virulence of the Wheat Pathogen <i>Parastagonospora nodorum</i>
ACS Chemical Biology 2020.0
The Genome of Tolypocladium inflatum: Evolution, Organization, and Expression of the Cyclosporin Biosynthetic Gene Cluster
PLoS Genetics 2013.0
Acrophiarin (antibiotic <scp>S31794</scp>/F‐1) from <i>Penicillium arenicola</i> shares biosynthetic features with both <i>Aspergillus</i>‐ and <i>Leotiomycete</i>‐type echinocandins
Environmental Microbiology 2020.0
Characterization of the Bafilomycin Biosynthetic Gene Cluster from <i>Streptomyces lohii</i>
ChemBioChem 2013.0