Tashiromine; a New Alkaloid from Maackia tashiroi

HETEROCYCLES
1990.0

Abstract

A new alkaloid (1) containing an indolizidine ring, named tashiromine, was isolated from the stems of Maackia tashiroi (Leguminosae) together with seven lupin alkaloids and ammodendrine. The structure of 1 was determined as (5S,6R)-5-hydroxymethyl-trans-indolizidine or its enantiomer by comparison of the spectral data with those of the synthetic diastereomers of 5-hydoxymethyl-trans-indolizidine. © 1990.

DOI： 10.3987/COM-89-S47

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