Using a method described previously [1], we investigated the carotenoid composition of the peel of the fruit of the hybrids Citrus sinensis Osb. (orange) with Azakhikan grapefruit and the peel of the fruit of C. ichagensis Sw. × Junos Tan. (Wilson citrus) [2]. The carotenoids were identified by spectrophotometry in the visible and ultraviolet regions of the spectrum, from the coloration and position of the zones on the chromatogram, by chromatograph of mixed samples of the isolated zones with known carotenoids, and by performing characteristic color reactions. The total amount of carotenoid pigments was determined by the colorometric method. The carotenoid complex of orange × Azakhikan grapefruit consists of 23 individual compounds, 18 of which have been identified, and the amount of vitamin-A-active carotenoids is 54% of the mass of carotenoids in the peel of the hybrid fruit. The carotenoid complex of the peel of Wilson citrus fruit consists of ten individual substances, eight of which have been identified, and the vitamin-A-active carotenoids amount to about 64% of the mass of all carotenoids in the complex.