Total Synthesis of Pyrrolidine and Piperidine Natural Products via TMSOTf-Mediated “5/6-endo-dig” Reductive Hydroamination of Enynyl Amines

Total Synthesis of Pyrrolidine and Piperidine Natural Products via TMSOTf-Mediated “5/6-endo-dig” Reductive Hydroamination of Enynyl Amines Catalytic enantioselective reductive alkynylation of amides enables one-pot syntheses of pyrrolidine, piperidine and indolizidine alkaloids Efficient Enantiomeric Synthesis of Pyrrolidine and Piperidine Alkaloids from Tobacco Total Synthesis of a Pyrroloindoloquinazoline Alkaloid Total synthesis of a piperidine alkaloid, microcosamine A Au-catalyzed stereodivergent synthesis of 2,5-disubstituted pyrrolidines: total synthesis of (+)-monomorine I and (+)-indolizidine 195B A Route to “all‐cis” 2‐Methyl‐6‐Substituted Piperidin‐3‐ol Alkaloids from syn‐(2R,1′S)‐2‐(1‐Dibenzylaminomethyl)epoxide: Rapid Total Synthesis of (+)‐Deoxocassine Synthesis of (+)-solenopsin via Pd-catalyzed N-alkylation and cyclization First total synthesis of pseudodistomin tetrahydroacetate An Intramolecular Hydroaminomethylation-Based Approach to Pyrrolizidine Alkaloids under Microwave-Assisted Heating