Pd‐Catalyzed Asymmetric Intramolecular Arylative Dearomatization of para‐Aminophenols^†

<scp>Pd‐Catalyzed</scp> Asymmetric Intramolecular Arylative Dearomatization of <scp>para‐Aminophenols</scp>^<b>†</b> Asymmetric Palladium‐Catalyzed Dearomative Intramolecular N‐Alkylation Reaction: Enantioselective Total Synthesis of (−)‐Spiroquinazoline Construction of the Erythrinane Core Skeleton via Asymmetric Catalytic Cascade Reaction of Tertiary Enamides Iridium‐Catalyzed Asymmetric Hydrogenation of 2,3‐Diarylallyl Amines with a Threonine‐Derived P‐Stereogenic Ligand for the Synthesis of Tetrahydroquinolines and Tetrahydroisoquinolines Total syntheses of (+)- and (−)-Crinane via Pd(0)-Catalyzed deacylative allylation Total syntheses of Hexahydropyrrolo[2,3-b]indole Alkaloids, (+)-pseudophrynamine 270 and (+)-pseudophrynamine 272A Complex Polyheterocycles and the Stereochemical Reassignment of Pileamartine A via Aza-Heck Triggered Aryl C–H Functionalization Cascades Asymmetric Total Synthesis of Biphenylquinolizidine Alkaloids 4″-O-Demethyllythridine and 14-epi-4″-O-Demethyllythridine Divergent Syntheses of Pyridoacridine Alkaloids via<scp>Palladium‐Catalyzed</scp> Reductive Cyclization with <scp>Nitro‐Biarenes</scp> Highly enantioselective Michael addition of 3-arylthio- and 3-alkylthiooxindoles to nitroolefins catalyzed by a simple cinchona alkaloid derived phosphoramide