Total syntheses of macleanine and lycoposerramine-S

Organic & Biomolecular Chemistry
2023.0

Abstract

Total syntheses of fawcettimine-class Lycopodium alkaloids having an imino bridge between C5 and C13 were accomplished. Fawcettimine was first prepared in 10 steps from a known compound, and the characteristic structures, including the imino bridge, were constructed via the formation of a bridgehead imine.

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