Agesasines A and B, Bromopyrrole Alkaloids from Marine Sponges Agelas spp

Marine Drugs
2020.0

Abstract

Exploration for specialized metabolites of Okinawan marine spongesAgelasspp. resulted in the isolation of five new bromopyrrole alkaloids, agesasines A (1) and B (2), 9-hydroxydihydrodispacamide (3), 9-hydroxydihydrooroidin (4), and 9E-keramadine (5). Their structures were elucidated on the basis of spectroscopic analyses. Agesasines A (1) and B (2) were assigned as rare bromopyrrole alkaloids lacking an aminoimidazole moiety, while3-5were elucidated to be linear bromopyrrole alkaloids with either aminoimidazolone, aminoimidazole, orN-methylated aminoimidazole moieties.

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