Unprecedented Reactivity of γ‐Amino Cyclopentenone Enables Diversity‐Oriented Access to Functionalized Indoles and Indole‐Annulated Ring Structures

Unprecedented Reactivity of γ‐Amino Cyclopentenone Enables Diversity‐Oriented Access to Functionalized Indoles and Indole‐Annulated Ring Structures Development of an Aza-Piancatelli-Templated Reaction Manifold from 4-Aminocyclopentenones: Access to Complex Carbocyclic Assemblies Construction of Octahydro‐4H‐cyclopenta[b]pyridin‐6‐one Skeletons using Pot, Atom, and Step Economy (PASE) Synthesis Rapid Construction of Hexacyclic Indolines via the Ru(II)-Catalyzed C–H Activation Initiated Cascade Cyclization of Phenidones with Enynones An unexpected reaction pathway in the synthesis of the ABCE framework of strychnine-type alkaloids – A multidisciplinary study Enantioselective Total Synthesis of (+)‐Nordasycarpidone, (+)‐Dasycarpidone, and (+)‐Uleine Concise Total Synthesis of Tronocarpine Phosphine‐Catalyzed (4+1) Annulation: Rearrangement of Allenylic Carbamates to 3‐Pyrrolines through Phosphonium Diene Intermediates Donor‐Acceptor Aminocyclobutane Monoesters: Synthesis and Silylium‐Catalyzed (4+2) Annulation with Indoles Synthesis of Pentahydroxylated Pyrrolizidines and Indolizidines