Spectroscopic analyses and chemical transformation for structure elucidation of two novel indole alkaloids from Gelsemium elegans

Tetrahedron Letters
2009.0

Abstract

Two new monoterpenoid oxindole alkaloids, gelsevanillidine (1) having an additional vanillin residue on gelsenicine-type alkaloid and gelseoxazolidinine (2) possessing an unusual oxazolidine ring, were isolated from Gelsemium elegans. To confirm their structures, the chemical transformation of a humantenine-type alkaloid into gelsevanillidine (1) and the deacetoxy derivative of gelseoxazolidinine was performed. © 2009 Elsevier Ltd. All rights reserved.

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