A biomimetic synthesis of a new skeletal Gelsemium alkaloid, 11-methoxy-19(R)-hydroxygelselegine

Tetrahedron
1994.0

Abstract

Based on a suggested biogenetic sequence, a sarpagine-type indole alkaloid, gardnerine (2), was stereoselectively converted to a new skeletal type Gelsemium alkaloid, 11-methoxy-19(R)-hydroxygelselegine (1), via a biogenetically hypothetical aziridine intermediate (17). © 1994.

DOI： 10.1016/S0040-4020(01)89296-6

Knowledge Graph

Similar Paper

A biomimetic synthesis of a new skeletal Gelsemium alkaloid, 11-methoxy-19(R)-hydroxygelselegine
Tetrahedron 1994.0
First Synthesis of the Novel Gelsemium Alkaloids, Gelselegine, Gelsenicine, and Gelsedine Using a Biomimetic Approach
The Journal of Organic Chemistry 1994.0
The first and biomimetic construction of the new skeleton of gelselegine-type oxindole alkaloids
The Journal of Organic Chemistry 1992.0
A biomimetic synthesis of a novel seco indole alkaloid, 11-methoxygelsemamide
Tetrahedron 1994.0
Structure Reinvestigation of Gelsemoxonine, a Constituent of Gelsemium elegans, Reveals a Novel, Azetidine-Containing Indole Alkaloid
Organic Letters 2003.0
Six new indole alkaloids from Gelsemium sempervirens Ait. f.
Tetrahedron Letters 2005.0
Six new indole alkaloids from Gelsemium sempervirens Ait. f.
Tetrahedron Letters 2005.0
Six new monoterpenoid indole alkaloids from the aerial part of Gelsemium elegans
Tetrahedron 2011.0
Two oxindole alkaloids from Gelsemium elegans
Phytochemistry 1990.0
Six new monoterpenoid indole alkaloids from the aerial part of Gelsemium elegans
Tetrahedron 2011.0