Synthesis of substituted 2H-benzo[e]indazole-9-carboxylate as a potent antihyperglycemic agent that may act through IRS-1, Akt and GSK-3β pathways

MedChemComm
2016.0

Abstract

Based on high throughput screening of our chemical library, we identified two 4,5-dihydro-2<i>H</i>-benzo[<i>e</i>]indazole derivatives (<b>5d</b> and <b>5g</b>), which displayed a significant effect on glucose uptake in L6 skeletal muscle cells. Based on these lead molecules, a series of benzo[<i>e</i>]indazole derivatives were prepared. Among all the synthesized dihydro-2<i>H</i>-benzo[<i>e</i>]indazoles, 8-(methylthio)-2-phenyl-6-<i>p</i>-tolyl-4,5-dihydro-2<i>H</i>-benzo[<i>e</i>]indazole-9-carboxylate (<b>5e</b>) showed significant glucose uptake stimulation in L6 skeletal muscle cells, even better than lead compounds. Additionally, <b>5e</b> decreased glucagon-induced glucose release in HepG2 hepatoma cells. The 2<i>H</i>-benzo[<i>e</i>]indazole <b>5e</b> exerted an antihyperglycemic effect in normal, sucrose challenged streptozotocin-induced diabetic rats and type 2 diabetic <i>db</i>/<i>db</i> mice. Treatment with <b>5e</b> at a dose of 30 mg kg<sup>-1</sup> in <i>db</i>/<i>db</i> mice caused a significant decrease in triglyceride and total cholesterol levels and increased the HDL-C level in a significant manner. The mechanistic studies revealed that the 2<i>H</i>-benzo[<i>e</i>]indazole <b>5e</b> significantly stimulated insulin-induced signaling at the level of IRS-1, Akt and GSK-3β in L6 skeletal muscle cells, possibly by inhibiting protein tyrosine phosphatase-1B. This new 2<i>H</i>-benzo[<i>e</i>]indazole derivative has potential for the treatment of diabetes with improved lipid profile.

Knowledge Graph

Similar Paper

Synthesis of substituted 2H-benzo[e]indazole-9-carboxylate as a potent antihyperglycemic agent that may act through IRS-1, Akt and GSK-3β pathways
MedChemComm 2016.0
Design, synthesis and biological evaluation of GY3-based derivatives for anti-type 2 diabetes activity
Bioorganic &amp; Medicinal Chemistry Letters 2015.0
Discovery of 3-(4-methanesulfonylphenoxy)-N-[1-(2-methoxy-ethoxymethyl)-1H-pyrazol-3-yl]-5-(3-methylpyridin-2-yl)-benzamide as a novel glucokinase activator (GKA) for the treatment of type 2 diabetes mellitus
Bioorganic &amp; Medicinal Chemistry 2014.0
Synthesis and in vivo antihyperglycemic activity of 5-(1H-pyrazol-3-yl)methyl-1H-tetrazoles
Bioorganic &amp; Medicinal Chemistry Letters 2005.0
Design, synthesis, and evaluation of benzofuran-based chromenochalcones for antihyperglycemic and antidyslipidemic activities
RSC Medicinal Chemistry 2023.0
Synthesis and Mechanism of Hypoglycemic Activity of Benzothiazole Derivatives
Journal of Medicinal Chemistry 2013.0
Synthesis and antihyperglycemic activity of phenolic C-glycosides
Bioorganic &amp; Medicinal Chemistry Letters 2011.0
Indazole-based ligands for estrogen-related receptor α as potential anti-diabetic agents
European Journal of Medicinal Chemistry 2017.0
Antidiabetic activity of N-(6-substituted-1,3-benzothiazol-2-yl)benzenesulfonamides
Bioorganic &amp; Medicinal Chemistry Letters 2008.0
Design and synthesis of 3,5-diarylisoxazole derivatives as novel class of anti-hyperglycemic and lipid lowering agents
Bioorganic &amp; Medicinal Chemistry 2009.0