Fluorescent H2 Receptor Squaramide-Type Antagonists: Synthesis, Characterization, and Applications

ACS Medicinal Chemistry Letters
2020.0

Abstract

Fluorescence labeled ligands have been gaining importance as molecular tools, enabling receptor-ligand-binding studies by various fluorescence-based techniques. Aiming at red-emitting fluorescent ligands for the hH<sub>2</sub>R, a series of squaramides labeled with pyridinium or cyanine fluorophores (<b>19</b>-<b>27</b>) was synthesized and characterized. The highest hH<sub>2</sub>R affinities in radioligand competition binding assays were obtained in the case of pyridinium labeled antagonists <b>19</b>-<b>21</b> (p<i>K</i> <sub>i</sub>: 7.71-7.76) and cyanine labeled antagonists <b>23</b> and <b>25</b> (p<i>K</i> <sub>i</sub>: 7.67, 7.11). These fluorescent ligands proved to be useful tools for binding studies (saturation and competition binding as well as kinetic experiments), using confocal microscopy, flow cytometry, and high content imaging. Saturation binding experiments revealed p<i>K</i> <sub>d</sub> values comparable to the p<i>K</i> <sub>i</sub> values. The fluorescent probes <b>21</b>, <b>23</b>, and <b>25</b> could be used to localize H<sub>2</sub> receptors in HEK cells and to determine the binding affinities of unlabeled compounds.

Knowledge Graph

Similar Paper

Fluorescent H<sub>2</sub> Receptor Squaramide-Type Antagonists: Synthesis, Characterization, and Applications
ACS Medicinal Chemistry Letters 2020.0
Red-Emitting Dibenzodiazepinone Derivatives as Fluorescent Dualsteric Probes for the Muscarinic Acetylcholine M<sub>2</sub> Receptor
Journal of Medicinal Chemistry 2020.0
Synthesis and pharmacological activity of fluorescent histamine H2 receptor antagonists related to potentidine
Bioorganic &amp; Medicinal Chemistry Letters 2003.0
Fluorescent-Labeled Selective Adenosine A<sub>2B</sub>Receptor Antagonist Enables Competition Binding Assay by Flow Cytometry
Journal of Medicinal Chemistry 2018.0
Synthesis and Characterization of High-Affinity 4,4-Difluoro-4-bora-3a,4a-diaza-s-indacene-Labeled Fluorescent Ligands for Human β-Adrenoceptors
Journal of Medicinal Chemistry 2011.0
Shining light on the histamine H2 receptor: Synthesis of carbamoylguanidine-type agonists as a pharmacological tool to study internalization
Bioorganic &amp; Medicinal Chemistry Letters 2021.0
Development of Fluorescent 4-[4-(3H-Spiro[isobenzofuran-1,4′-piperidin]-1′-yl)butyl]indolyl Derivatives as High-Affinity Probes to Enable the Study of σ Receptors via Fluorescence-Based Techniques
Journal of Medicinal Chemistry 2023.0
Fluorescent ligands for adenosine receptors
Bioorganic &amp; Medicinal Chemistry Letters 2013.0
Synthesis, Biological Evaluation, and Utility of Fluorescent Ligands Targeting the μ-Opioid Receptor
Journal of Medicinal Chemistry 2015.0
A Versatile Sub-Nanomolar Fluorescent Ligand Enables NanoBRET Binding Studies and Single-Molecule Microscopy at the Histamine H<sub>3</sub> Receptor
Journal of Medicinal Chemistry 2021.0