Plant Growth Substances in the Young Fruit ofCitrus unshiu

Agricultural and Biological Chemistry
1971.0

Abstract

In the course of our study to clarify the mechanism of physiological abscission of the young fruit of Citrus unshiu, we are investigating the hormonal balance in the young fruit. Khalifah et al. have suggested the occurrence of the non-indolic auxin, citrus auxin, in the fruit and seed of Citrus species. Goren and Goldschmidt have reported the occurrence in Citrus sinensis of some promoters, which are different from indoleacetic acid (IAA) and citrus auxin, and quite recently Goldschmidt et al. the identification of IAA in Citrus stem. We report here the isolation of IAA and indoleacetamide (IAM) from the very young fruit of Citrus unshiu. On the other hand we could not find any indication for the occurrence of the so called "citrus auxin." The young fruit (10 kg) was harvested one week after full bloom and was extracted with peroxide-free ether and successively with methanol by use of blender. Each extract was separated into fractions A, B, C and D by solvent extraction. Fractions A, C and D were separately purified by specific procedures, with purification steps guided by the Avena curvature test and TLC sprayed with Ehrlich reagent. Successive purification of fraction A afforded 3.5 mg of crystalline powder identified as IAA by comparison of TLC Rf values, gas chromatography retention times, UV and mass spectra with authentic IAA. Fraction C was shown to contain IAA (content 3 mg estimated by Avena curvature test and gas chromatography) and yielded 13 mg of crystalline IAM identified by comparison with an authentic sample. Fraction D yielded another 40 mg of IAM and 90 mg of a tryptophane-containing peptide. This experiment disclosed that the young fruit of Citrus unshiu contains 0.5~1 mg/kg (ca. 0.2 μg/fruit) of IAA and 5 mg/kg (ca. 1 μg/fruit) of IAM. Any other fractions except those containing IAA and IAM did not reveal appreciable auxin-like activity, indicating the absence of citrus auxin.

Knowledge Graph

Similar Paper

Plant Growth Substances in the Young Fruit of<i>Citrus unshiu</i>
Agricultural and Biological Chemistry 1971.0
Structures of New Cyclic Peptides in Young Unshiu (<i>Citrus unshiu</i>M<scp>arcov</scp>.), Orange (<i>Citrus sinensis</i>O<scp>sbeck</scp>.) and Amanatsu (<i>Citrus natsudaidai</i>) Peelings
Agricultural and Biological Chemistry 1991.0
Occurrence of Indoleacetaldehyde and Tryptophol in the Extracts of Etiolated Shoots of <i>Pisum</i> and <i>Helianthus</i> Seedlings
Physiologia Plantarum 1967.0
Identification and quantification of three active auxins in different tissues of <i>Tropaeolum majus</i>
Physiologia Plantarum 2002.0
Isolation of Two New IAA Conjugates, 7’<i>O</i>-β<scp>-d-</scp>Glucopyranoside of 3,7-Dihydroxy-2-Indolinone-3-Acetic Acid and 8’<i>-O-</i>-<scp>d</scp>-Glucopyranoside of 8-Hydroxy-2-Quinolone-4-Carboxylic Acid, from Immature Sweet Corn Kernels (<i>Zea mays</i>L)
Agricultural and Biological Chemistry 1987.0
Constituents of Domestic Citrus Plants. Part XXVI. Studies on the Constituents of Yalaha. Structures of a New Acridone Alkaloid and Two New Coumarins.
Chemical and Pharmaceutical Bulletin 1996.0
Light-induced auxin-inhibiting substance from cabbage (Brassica oleacea L.) shoots
Tetrahedron Letters 1997.0
Acridone alkaloids. VII. Constituents of Citrus sinensis Osbeck var. brasiliensis Tanaka. Isolation and characterization of three new acridone alkaloids, and a new coumarin.
Chemical and Pharmaceutical Bulletin 1983.0
Indole-3-acetyl-myo-inositol in kernels of Oryza sativa
Phytochemistry 1980.0
3-(p-Hydroxyphenyl)-Propionic Acid Amide (Phloretamide) in Fruits of Malus
Biochemie und Physiologie der Pflanzen 1986.0