<jats:title>Abstract</jats:title><jats:p>Three new <jats:italic>Daphniphyllum</jats:italic> alkaloids, daphlongeranines C–E (<jats:bold>1</jats:bold>–<jats:bold>3</jats:bold>), along with 13 known ones, were isolated from the fruits of <jats:italic>Daphniphyllum longeracemosum.</jats:italic> Their structures were elucidated on the basis of extensive spectroscopic analyses, especially 2D‐NMR experiments.