1. From the epigeal part of Veratrum lobelianum collected in Dzhergalan we have isolated the formerly unknown alkaloids obtained previously from the epigeal part of V. lobelianum collected in the Karkara valley: veralosine, veralosinine, veratroylzygadenine, and the new alkaloid germinaline. 2. The structure of germinaline has been established as 16β-acetyl-15α-(d-2-hydroxy-2-methylbutyryl)-3β-(l-2-methylbutyryl)germine. © 1974 Consultants Bureau.