<jats:title>Abstract</jats:title><jats:p>Four new coumarins, <jats:bold>1</jats:bold>–<jats:bold>4</jats:bold>, and two new triterpenes, <jats:bold>5</jats:bold> and <jats:bold>6</jats:bold>, along with nine known compounds have been identified from the leaves of <jats:italic>Calophyllum inophyllum</jats:italic> on the basis of spectroscopic analyses and chemical methods. The structure of apetalolide (<jats:bold>7</jats:bold>), previously reported from <jats:italic>C. apetalum</jats:italic>, was revised by means of 2D‐NMR, and the absolute configuration of the known compound inophyllum D (<jats:bold>8</jats:bold>) was established by a modified <jats:italic>Mosher</jats:italic>'s method.