Two new natural products, o-(a-L-rhamnopyranosyloxy)benzylamine and o-hydroxybenzylamine, have been isolated from flowers of Reseda odorata L. The proposed structures have been confirmed by transformation of the rhamnoside into N-[o-(O-triacetyl-a-L-rhamnopyranosyloxy)benzyl]acetamide and by synthesis of this amide and the two amines. A possible biogenetic relationship between the amines and glucosinolates is briefly discussed.