Jasonol, a rare tricyclic eudesmane sesquiterpene and six other new sesquiterpenoids from Jasonia candicans

Tetrahedron
1998.0

Abstract

The extract of the leaves of Jasonia candicans yielded seven new sesquiterpenes and sesquiterpene lactones including a eudesmane containing a rare type of 6/6/4 membered ring system, two 7-epi-eudesmanes (12-hydroxyisointermedeol and 7-epi-ilicic acid), two guaianolides (inuviscolide and its 8-epi- derivative), iphionane and cadinane-triol derivatives. The structures were elucidated by spectroscopic analysis particularly high-resolution 1D and 2D NMR spectroscopy and the extensive NOE analysis.

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