The Mechanisms of Radical SAM/Cobalamin Methylations: An Evolving Working Hypothesis.

The Mechanisms of Radical SAM/Cobalamin Methylations: An Evolving Working Hypothesis. Formation of 2-methyltryptophan in the biosynthesis of thiostrepton: Isolation of S-adenosylmethionine: Tryptophan 2-methyltransferase Watasemycin biosynthesis in Streptomyces venezuelae: thiazoline C-methylation by a type B radical-SAM methylase homologue Thiostrepton Maturation Involving a Deesterification−Amidation Way To Process the C-Terminally Methylated Peptide Backbone Menaquinone Biosynthesis: Formation of Aminofutalosine Requires a Unique Radical SAM Enzyme Characterization of <i>N</i>‐Demethyllincosamide Methyltransferases LmbJ and CcbJ Structure-guided discovery of the metabolite carboxy-SAM that modulates tRNA function Thiostrepton Biosynthesis: Prototype for a New Family of Bacteriocins 3'-Demethoxy-3'-hydroxystaurosporine-O-methyltransferase from Streptomyces longisporoflavus Catalyzing the Last Step in the Biosynthesis of Staurosporine. Molecular Architecture of TylM1 from <i>Streptomyces fradiae</i>: An <i>N</i>,<i>N</i>-Dimethyltransferase Involved in the Production of dTDP-<scp>d</scp>-mycaminose,