24-Methylene-25-methylcholesterol, 24-ethyldesmosterol and clerosterol in addition to several common phytosterols were identified in immature seed of Phaseolus vulgaris. 24-Methylene-25-methylcholesterol is considered closely correlated biogenetically with 25-methyldolichosterone, a brassinosteroid recently isolated from the same plant material, because both of them have the same basic side-chain structure.