Chaetochromin, a bis(naphthodihydropyran-4-one) mycotoxin from Chaetomium thielavioideum: Application of 13C-1H long-rang coupling to the structure elucidation.

Chemical and Pharmaceutical Bulletin
1980.0

Abstract

Details of the separation of the metabolites (I-V) of Chaetomium thielavioideum are presented. The structure of a new mycotoxin named chaetochromin was studied by physical method (ultraviolet, infrared, 1H- and 13C-nuclear magnetic resonance (NMR), and mass spectrum) and it was identified as the bis(naphthodihydropyran-4-one (II). The assignment of the 13C-NMR signals was largely achieved with the aid of the two- and threebond spin-spin couplings between 13C and 1H.

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