<jats:title>Abstract</jats:title><jats:p>Four new 11‐noriridoids named scholareins A–D (<jats:bold>1</jats:bold>–<jats:bold>4</jats:bold>), along with three known derivatives, isoboonein (<jats:bold>5</jats:bold>), alyxialactone (<jats:bold>6</jats:bold>), and loganin (<jats:bold>7</jats:bold>), were isolated from EtOH extracts of the bark of <jats:italic>Alstonia scholaris</jats:italic> by chromatographic methods. Their structures were identified by extensive mass‐spectrometric and spectroscopic (especially 2D‐NMR) experiments.