Two‐Step Catalytic Transformation ofN‐Benzyllactams to Alkaloids (±)‐Solenopsin, (±)‐Solenopsin A, and (+)‐Julifloridine

Two‐Step Catalytic Transformation ofN‐Benzyllactams to Alkaloids (±)‐Solenopsin, (±)‐Solenopsin A, and (+)‐Julifloridine Catalytic enantioselective reductive alkynylation of amides enables one-pot syntheses of pyrrolidine, piperidine and indolizidine alkaloids A General Iridium-Catalyzed Reductive Dienamine Synthesis Allows a Five-Step Synthesis of Catharanthine via the Elusive Dehydrosecodine Synthesis of (+)-solenopsin via Pd-catalyzed N-alkylation and cyclization Controlling stereoselectivity by enzymatic and chemical means to access enantiomerically pure (1S,3R)-1-benzyl-2,3-dimethyl-1,2,3,4-tetrahydroisoquinoline derivatives Total Synthesis of Pyrrolidine and Piperidine Natural Products via TMSOTf-Mediated “5/6-endo-dig” Reductive Hydroamination of Enynyl Amines Divergent Syntheses of Pyridoacridine Alkaloids via<scp>Palladium‐Catalyzed</scp> Reductive Cyclization with <scp>Nitro‐Biarenes</scp> Concise synthesis of bicyclic iminosugars via reductive functionalization of sugar-derived lactams and subsequent RCM reaction The Enantioselective Synthesis of Eburnamonine, Eucophylline, and 16′‐epi‐Leucophyllidine Ir-Catalyzed Asymmetric Total Syntheses of Bisdehydrotuberostemonine D, Putative Bisdehydrotuberostemonine E and Structural Revision of the Latter