Three new alkaloids designated as cyclostachine A (2), cyclostachine B (7) and cyclopiperstachine (10) have been isolated from Piper trichostachyon C. DC. Their structures have been derived on the basis of spectral and degradative studies and confirmed by synthesis. The 1H‐ and 13C‐NMR. spectra of these compounds are discussed. Copyright © 1975 Verlag GmbH & Co. KGaA, Weinheim