The enantiocontrolled total synthesis of natural (–)-goniomitine

J. Chem. Soc., Chem. Commun.
2004.0

Abstract

The first enantiocontrolled total synthesis of (-)-goniomitine, a new structural type of indole alkaloid of the Aspidosperma family isolated from the root bark of Gonioma malagasy, has been completed starting from a chiral cyclopentadienone synthon and establishes the absolute stereochemistry as 20R, 21S.

DOI： 10.1039/C39910000462

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