Dry woody stems of Limonia acidissima L. (Rutaceae) purchased from the market in Pagan, Burma, were powdered and extracted with cold EtOH. The extracts were partitioned between H₂O and petroleum ether, then between H₂O and CHCl₃. The combined petroleum ether and CHCl₃ extracts (nearly identical in composition by TLC) were separated using silica gel column and thin layer chromatography without acid treatment. A wide range of known natural products was obtained, including quinolones (4-methoxy-2-quinolone, edulitine, 4-methoxy-1-methyl-2-quinolone), the anthraquinone physcion, limonoids (limonin, methyl deacetylnominilate), amides (tembamide, N-(p-hydroxy-β-phenethyl)-p-hydroxycinnamide), the lignan (±)-syringaresinol, and indole derivatives (N,N-dimethyltryptamine, 3-formylindole, 2-methyltetrahydro-β-carboline). Additionally, three new simple indole alkaloids were isolated: N(b)-acetyl-N(b)-methyltryptamine (1), (+)-tanakine (2), and (+)-tanakamine (4). The structures of the new compounds were elucidated by UV, IR, MS, and NMR spectral data, as well as chemical reactions such as acetylation.