Biosynthetic Hypothesis-Guided Discovery and Total Syntheses of PKS–NRPS Hybrid Metabolites from Endophytic Fungus Periconia Species

Biosynthetic Hypothesis-Guided Discovery and Total Syntheses of PKS–NRPS Hybrid Metabolites from Endophytic Fungus <i>Periconia</i> Species Pericoannosin A, a Polyketide Synthase–Nonribosomal Peptide Synthetase Hybrid Metabolite with New Carbon Skeleton from the Endophytic Fungus <i>Periconia</i> sp. Periconiasins A–C, New Cytotoxic Cytochalasans with an Unprecedented 9/6/5 Tricyclic Ring System from Endophytic Fungus <i>Periconia</i> sp. Periconiasins I and J, two new cytochalasans from an endophytic fungus Periconia sp. Periconiasin G, a new cytochalasan with unprecedented 7/6/5 tricyclic ring system from the endophytic fungus Periconia sp. Isocoumarindole A, a Chlorinated Isocoumarin and Indole Alkaloid Hybrid Metabolite from an Endolichenic Fungus Aspergillus sp. Isocoumarindole A, a Chlorinated Isocoumarin and Indole Alkaloid Hybrid Metabolite from an Endolichenic Fungus <i>Aspergillus</i> sp. Novel secondary metabolites from the endobryophytic fungus Botrysphaeria laricina and their biological activity Four new monoterpenoids from an endophytic fungus <i>Periconia</i> sp. F-31 Discovery and Characterization of a PKS–NRPS Hybrid in <i>Aspergillus terreus</i> by Genome Mining