HIGH-PERFORMANCE LIQUID CHROMATOGRAPHIC METHOD FOR THE DETERMINATION OF OCCUPATIONAL EXPOSURE TO THE PESTICIDE ABAMECTIN

American Industrial Hygiene Association Journal
1991.0

Abstract

As part of a survey of occupational exposure to pesticides in greenhouses for growing ornamentals, analytical methods were developed and validated for the measurement of exposure of workers to the pesticide abamectin. Abamectin consists of a mixture of avermectin-B1a and avermectin-B1b, which are members of a class of fermentation products of the soil microorganism Streptomyces Avermitilis. Because of the high molecular weight of the avermectins (greater than 800 daltons), high-performance liquid chromatography (HPLC) was the analytical method of choice. Previously described HPLC methods that used fluorescence detection were adapted and validated for the determination of dermal exposure by the analysis of cotton gloves and foliar dislodgeable residue. IOM samplers (developed at the Institute of Occupational Medicine, Edinburgh, U.K.) for collecting the inspirable fraction of dust or aerosols were tested for the determination of airborne abamectin concentrations in greenhouses. An analytical procedure considerably simpler than published methods appeared suitable for the determination of abamectin residues on cotton gloves and on greenhouse foliage. Analytical recovery from cotton gloves, solutions of foliar dislodgeable residues, and air-sampling filters was essentially complete. However, air concentrations of abamectin could not be reliably measured by using the IOM sampling device because of breakdown during sampling. Between-day coefficients of variation for solutions of dislodgeable residue and cotton glove extracts were between 3% and 6% for abamectin concentrations between 5 and 140 micrograms/L.

Knowledge Graph

Similar Paper

HIGH-PERFORMANCE LIQUID CHROMATOGRAPHIC METHOD FOR THE DETERMINATION OF OCCUPATIONAL EXPOSURE TO THE PESTICIDE ABAMECTIN
American Industrial Hygiene Association Journal 1991.0
Determination of abamectin in citrus fruits using SPE combined with dispersive liquid–liquid microextraction and HPLC–UV detection
Journal of Separation Science 2013.0
Analysis by HPLC of Ryanodine and Dehydroryanodine Residues on Fruits and in Ryania Powdery Wood
Journal of Agricultural and Food Chemistry 2001.0
Solid phase microextraction gas chromatographic analysis of organophosphorus pesticides in biological samples
Journal of Chromatography B 2005.0
Determination of the Naturally Derived Insect Control Agent Spinosad in Cottonseed and Processed Commodities by High-Performance Liquid Chromatography with Ultraviolet Detection
Journal of Agricultural and Food Chemistry 1996.0
Determination of Atropine Residues in Beef by High Performance Liquid Chromatography
Pakistan Journal of Zoology 2022.0
Simultaneous assay for amatoxins and phallotoxins in Amanita phalloides Fr. by high-performance liquid chromatography
Journal of Chromatography A 1992.0
Analysis of ergopeptine alkaloids in endophyte-infected tall fescue
Journal of Agricultural and Food Chemistry 1988.0
Determination of non-protein amino acids and toxins in Lathyrus by high-performance liquid chromatography with precolumn phenyl isothiocyanate derivatization
Journal of Chromatography A 1994.0
Paspalitrem C, a new metabolite from sclerotia of Claviceps paspali
Journal of Agricultural and Food Chemistry 1984.0