<jats:p> Countercurrent distribution of the alkaloids of Lycopodiumannotinum gave four new bases: annofoline, lycofoline, and α- and β-lofoline. Annofoline, C<jats:sub>16</jats:sub>H<jats:sub>25</jats:sub>O<jats:sub>2</jats:sub>N, contained a keto and a hydroxyl group. Lycofoline, C<jats:sub>16</jats:sub>H<jats:sub>25</jats:sub>O<jats:sub>2</jats:sub>N, possessed at least one hydroxyl group and possibly a double bond, α- and β-Lofoline each had the formula C<jats:sub>18</jats:sub>H<jats:sub>29</jats:sub>O<jats:sub>3</jats:sub>N and contained a hydroxyl and an O-acetyl group.