A new cinnamide derivative together with N (p-hydroxyphenylethyl) p-coumaramide and vanillic acid has been isolated from the stems of Solanum verbascifolium L., the structure of the new compound was elucidated as N-2-hydroxy-2 (p-hydroxyphenylethyl) p-coumaramide (1) on the basis of physical and chemical evidence and spectral analysis.