From the epigeal part of Scopolia tangutica Maxim. grown in the Leningrad oblast under crop conditions, by adsorption column chromatography and selective elution we have isolated two more alkaloids in addition to hyoscyamine and scopolamine: base I and base II. Base I has the structure of an ester of scopine with α-phenyl-α,β-dihydroxypropionic acid and is identical with anisodine. Base II has the structure of 6-hydroxyhyoscyarnine.