A Total Synthesis of Millingtonine A

Organic Letters
2012.0

Abstract

A total synthesis of millingtonine A, a diglycosylated alkaloid, has been accomplished. Millingtonine A possesses a unique racemic tricyclic core structure not known from any other natural or synthetic source until now. The synthesis features a key bond-forming radical Ueno - Stork cyclization to form the heterocyclic core. © 2012 American Chemical Society.

DOI： 10.1021/ol203158p

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