Six 14-membered cyclopeptide alkaloids, i.e., ramosines A - C, mucronine J, and lotusines A and D, were isolated from the roots of Paliurus ramosissimus, and an additional four, hemsines A - D, from the roots of P. hemsleyanus. Among these, ramosines A - C (1, 5, and 6, resp.) and hemsines A and B (7 and 8, resp.) are new bases of the amphibine-B type, and hemsines C and D (9 and 10, resp.) are new integerrine-type alkaloids. Additionally, ramosine C (6) represents the first 14-membered cyclopeptide alkaloid possessing a substitution (-OH) at C(13′). Their structural elucidations were based on spectral analysis and molecular-modeling studies. Pronounced solvent effects in the 1H- and 13C-NMR spectra of these two types of alkaloids were observed.