Three new indole alkaloids, 10-methoxy-16-de(methoxycarbonyl)pagicerine (1), (5 beta)-17-O-deacetyl-5,11-dimethoxyakuammiline (2), and ((16S, 19E)-N-1-(hydroxymethyl)isositsirikine (3) were isolated from the roots of Razivolfia yunnanensis, together with seven known alkaloids. The structures of the new compounds were elucidated by in-depth spectroscopic and mass-spectrometric analyses.