Four new Daphniphyllum alkaloids, daphlongamines E-H (1-4, resp.), along with 19 known alkaloids, were isolated from the leaves of Daphniphyllum longeracemosum. Their structures were characterized by spectroscopic methods, especially 2D-NMR techniques. It is noteworthy that aconitineand veatchine-type diterpenoid alkaloids were also isolated from this species. © 2009 Verlag Helvetica Chimica Acta AG.