Studies on the Degradation of Kopsine, the Alkaloid of Kopsia fruticosa. II

Journal of the American Chemical Society
1953.0

Abstract

Kopsine, C22H26O4N2, the alkaloid of Kopsia fruticosa, on mild degradation with aqueous and alcoholic alkali produces two new bases—kopsidine, C20H24O3N2, m.p. 142° (dec.) and kopsidinine, C19H22O2N2, m.p. 248° (dec.), which is free from methoxy. Their isolation, analyses, properties and ultraviolet absorption curves have been described. Kopsine produces 2-methylindole, C9H9N, m.p. 57°; indole-2-carboxylic acid, C9H7O2N, m.p. 199°; and an uncharacterized base (in traces) on fusion with potassium hydroxide. © 1953, American Chemical Society. All rights reserved.

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